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Reversible On-Off Switching of a Single-Molecule Magnet via a Crystal-to-Crystal Chemical Transformation. | LitMetric
Dynamic molecular crystals are of high interest due to their potential applications. Herein we report the reversible on-off switching of single-molecule magnet (SMM) behavior in a [Mo(CN)] based molecular compound. Upon dehydration and rehydration, the trinuclear MnMo molecule [Mn(L)(HO)][Mo(CN)]·2HO (1) undergoes reversible crystal-to-crystal transformation to a hexanuclear MnMo compound [Mn(L)(HO)][Mn(L)][Mo(CN)] (2). This structural transformation involves the breaking and reforming of coordination bonds which leads to significant changes in the color and magnetic properties. Compound 1 is an SMM with an energy barrier of 44.9 cm, whereas 2 behaves as a simple paramagnet despite its higher ground state spin value. The distortion of the pentagonal bipyramidal geometry of [Mo(CN)] in 2 disrupts the anisotropic exchange interactions that lead to SMM behavior in 1.
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