A substrate surface on which gold particles are distributed is prepared by annealing an ultra-thin gold film to enable glancing angle deposition. By cooling the substrate and controlling its spin rate, two spiral-like and one screw-like gold nanohelix arrays are grown upon the seeded surfaces. The mean helix radius and pitch length are reduced to 17 and 55 nm, respectively. The g-factor of the three nanohelix arrays is measured here and associated circular dichroism peak blue shifts occur as the gold helices shrink.
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http://dx.doi.org/10.1186/s11671-017-2261-z | DOI Listing |
ACS Appl Mater Interfaces
August 2023
CNRS, Univ. Bordeaux, Bordeaux INP, ICMCB, UMR 5026, 87 avenue du Dr. A. Schweitzer, Pessac F-33608, France.
Flexible strain sensors based on nanoparticle (NP) arrays show great potential for future applications such as electronic skin, flexible touchscreens, healthcare sensors, and robotics. However, even though these sensors can exhibit high sensitivity, they are usually not very stable under mechanical cycling and often exhibit large hysteresis, making them unsuitable for practical applications. In this work, strain sensors based on silica nanohelix (NH) arrays grafted with gold nanoparticles (AuNPs) can overcome these critical aspects.
View Article and Find Full Text PDFJ Chem Phys
July 2023
Center for Soft Nanoscience, University of Münster, 48149 Münster, Germany.
We investigate the electron emission from 3D chiral silver alloy nanohelices initiated by femtosecond laser pulses with a central photon energy of hν = 1.65 eV, well below the work function of the material. We find hot but thermally distributed electron spectra and a strong anisotropy in the electron yield with left- and right-circularly polarized light excitations, which invert in sign between left- and right-handed helices.
View Article and Find Full Text PDFMater Horiz
January 2021
CNR NANOTEC Institute of Nanotechnology, Via Monteroni, Lecce 73100, Italy.
In this work we report the local growth of ordered arrays of 3D core-shell chiral nanohelices based on plasmonic gallium metal. The structures can be engineered in a single step using focused ion beam induced deposition, where a Ga ion source is used to shape the metallic nanohelix core, while the dielectric precursor is dissociated to create dielectric shells. The solubility of gallium in the different investigated dielectric matrices controls the core-shell thickness ratio of the nanohelices.
View Article and Find Full Text PDFSmall
November 2021
School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), 50 UNIST-gil, Ulsan, 44919, South Korea.
ACS Nano
September 2021
Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, People's Republic of China.
TiO nanohelices (NHs) have attracted extensive attention owing to their high aspect ratio, excellent flexibility, elasticity, and optical properties, which endow promising performances in a vast range of vital fields, such as optics, electronics, and micro/nanodevices. However, preparing rigid TiO nanowires (TiO NWs) into spatially anisotropic helical structures remains a challenge. Here, a pressure-induced hydrothermal strategy was designed to assemble individual TiO NWs into a DNA-like helical structure, in which a Teflon block was placed in an autoclave liner to regulate system pressure and simulate a cell-rich environment.
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