The construction of liquid crystal compositions consisting of the dimeric liquid crystal, (cyanobiphenyl dimer = 1'',9''-bis(4-cyanobiphenyl-4'-yl)nonane), and the range of nematic systems is explored. The materials include a laterally functionalized monomer, which was used to construct a phase diagram with , as well as one laterally linked dimer liquid crystal material and two liquid crystal gold nanoparticle (LC-Au-NPs) systems. For the Au-NP-LCs, the NP diameters were varied between ~3.3 nm and 10 nm. Stable mixtures that exhibit a nematic-nematic phase transition are reported and were investigated by POM (polarizing optical microscopy), DSC (differential scanning calorimetry) and X-ray diffraction studies.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5453202PMC
http://dx.doi.org/10.3390/ma7053494DOI Listing

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