Sorption characteristic of uranium(VI) ion onto K-feldspar.

Appl Radiat Isot

Radiochemistry Lab, School of Nuclear Science and Technology, Lanzhou University, 730000 Lanzhou, China; Key Laboratory of Special Function Materials and Structure Design, Ministry of Education, Lanzhou University, 730000 Lanzhou, China. Electronic address:

Published: October 2017

The effect of pH, contact time, temperature, ionic strength and initial U(VI) concentration on U(VI) sorption onto K-feldspar was investigated using batch techniques. The sorption kinetics was evaluated and the activation energy was obtained based on the rate constants at different temperature. Graphical correlations of sorption isotherm models have been evaluated and applied for U(VI) uptake by K-feldspar. Various thermodynamic parameters, such as, Gibb's free energy, entropy and enthalpy of the on-going sorption process have been calculated and the possible sorption mechanism of U(VI) was deduced. The results are expected to help better understand the migration of uranium in the host materials of granite.

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http://dx.doi.org/10.1016/j.apradiso.2017.07.041DOI Listing

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