Download full-text PDF

Source
http://dx.doi.org/10.1021/acs.inorgchem.7b01753DOI Listing

Publication Analysis

Top Keywords

correction thiolate
4
thiolate spin
4
spin population
4
population type
4
type copper
4
copper azurin
4
azurin derived
4
derived hyperfine
4
hyperfine coupling
4
correction
1

Similar Publications

Article Synopsis
  • The study focuses on creating a stable and efficient gold (Au) catalyst for electrocatalysis by using a carbon support and synthesizing Au clusters that are highly loaded and atomically precise.
  • Researchers synthesized heterogeneous Au catalysts by heating a specific thiolate complex on carbon, which successfully produced smaller and more stable Au clusters when using D2S ligands compared to PET.
  • The D2S-modified catalysts displayed greater durability in hydrogen evolution reactions, attributed to their ability to better prevent aggregation during the process, highlighting the importance of ligand design for catalyst stability.
View Article and Find Full Text PDF

Metal-ligand bond in group-11 complexes and nanoclusters.

Phys Chem Chem Phys

August 2024

Department of Chemistry, Nanoscience Center, University of Jyväskylä, FI-40014 Jyväskylä, Finland.

Density functional theory is used to study geometric, energetic, and electronic properties of metal-ligand bonds in a series of group-11 metal complexes and ligand-protected metal clusters. We study complexes as the forms of M-L (L = SCH, SCH, PPh, NHC, NHC, NHC, NHC, CCMe, CCPh) and L-M-L (L = NHC, PPh, and L = CCPh). Furthermore, we study clusters denoted as [MLBr] (L = PPh, NHC, NHC, NHC, NHC).

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!