Microstructural Evolution, Thermodynamics, and Kinetics of Mo-Tm₂O₃ Powder Mixtures during Ball Milling.

The microstructural evolution, thermodynamics, and kinetics of Mo (21 wt %) Tm₂O₃ powder mixtures during ball milling were investigated using X-ray diffraction and transmission electron microscopy. Ball milling induced Tm₂O₃ to be decomposed and then dissolved into Mo crystal. After 96 h of ball milling, Tm₂O₃ was dissolved completely and the supersaturated nanocrystalline solid solution of Mo (Tm, O) was obtained. The Mo lattice parameter increased with increasing ball-milling time, opposite for the Mo grain size. The size and lattice parameter of Mo grains was about 8 nm and 0.31564 nm after 96 h of ball milling, respectively. Ball milling induced the elements of Mo, Tm, and O to be distributed uniformly in the ball-milled particles. Based on the semi-experimental theory of Miedema, a thermodynamic model was developed to calculate the driving force of phase evolution. There was no chemical driving force to form a crystal solid solution of Tm atoms in Mo crystal or an amorphous phase because the Gibbs free energy for both processes was higher than zero. For Mo (21 wt %) Tm₂O₃, it was mechanical work, not the negative heat of mixing, which provided the driving force to form a supersaturated nanocrystalline Mo (Tm, O) solid solution.