Optimization of Layered Cathode Materials for Lithium-Ion Batteries.

Materials (Basel)

Physicochimie des Electrolytes et Nanosystèmes Interfaciaux (PHENIX), Sorbonne Universités, UPMC Univ. Paris 06, CNRS UMR 8234, 4 place Jussieu, Paris 75005, France.

Published: July 2016

This review presents a survey of the literature on recent progress in lithium-ion batteries, with the active sub-micron-sized particles of the positive electrode chosen in the family of lamellar compounds LiO₂, where stands for a mixture of Ni, Mn, Co elements, and in the family of Li₂MnO₃•(1 - )LiNiMnO₂ layered-layered integrated materials. The structural, physical, and chemical properties of these cathode elements are reported and discussed as a function of all the synthesis parameters, which include the choice of the precursors and of the chelating agent, and as a function of the relative concentrations of the cations and composition . Their electrochemical properties are also reported and discussed to determine the optimum compositions in order to obtain the best electrochemical performance while maintaining the structural integrity of the electrode lattice during cycling.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5456936PMC
http://dx.doi.org/10.3390/ma9070595DOI Listing

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