We describe how the contribution of crystallographic texture to the anisotropy of the resistivity of polycrystalline samples can be estimated by averaging over crystallographic orientations through a geometric mean approach. The calculation takes into account the orientation distribution refined from neutron diffraction data and literature values for the single crystal resistivity tensor. The example discussed here is a melt-cast processed Bi₂Sr₂CaCu₂O (Bi-2212) polycrystalline tube in which the main texture component is a <010> fiber texture with relatively low texture strength. Experimentally-measured resistivities along the longitudinal, radial, and tangential directions of the Bi-2212 tube were compared to calculated values and found to be of the same order of magnitude. Calculations for this example and additional simulations for various texture strengths and single crystal resistivity anisotropies confirm that in the case of highly anisotropic phases such as Bi-2212, even low texture strengths have a significant effect on the anisotropy of the resistivity in polycrystalline samples.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5459035 | PMC |
http://dx.doi.org/10.3390/ma10050534 | DOI Listing |
To modify the sensitivity and melting point of the casting of DNTF, a eutectic system of insensitive explosive 3,5,5-trinitro-1,3-oxazinane (TNTON) and DNTF was prepared through a new method. The melting and liquefaction processes of TNTON/DNTF at different ratios were investigated, and a phase diagram was established. The melting and decomposition processes of TNTON, DNTF, and TNTON/DNTF eutectic at different heating rates were compared, while the sensitivity tests were conducted to study the desensitizing effect of TNTON on DNTF.
View Article and Find Full Text PDFThe synthesis and characterization of low-melting-point insensitive energetic materials are crucial due to their increasing applications in melt-cast explosives. In this work, a furazan-derived energetic compound, 3,4-bis[3(2-azidoethoxy)furazan-4-yl]furoxan (DAeTF), exhibiting insensitive and high-energy characteristics, is rationally designed and synthesized. The structure of DAeTF is characterized by nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, elemental analysis, mass spectrometry, and single-crystal X-ray diffraction.
View Article and Find Full Text PDFACS Omega
May 2023
National Special Superfine Powder Engineering Research Center of China, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
To eliminate internal defects of grains developed during melt-cast charging, the formation mechanism and the trend of crystal morphology of internal defects of 2,4,6-trinitrotoluene and 2,4-dinitroanisole-based melt-cast explosives under different process conditions were simulated. The effects of solidification treatment on melt-cast explosive molding quality were investigated by combining pressurized feeding, head insulation, and water bath cooling. The single pressurized treatment technology results showed that grains were exposed to layer-by-layer solidification from outside to inside, resulting in V-shaped shrink areas of the contract cavity in the core.
View Article and Find Full Text PDFPolymers (Basel)
March 2023
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China.
As a matrix for melt-cast explosives, 3,4-dinitropyrazole (DNP) is a promising alternative to 2,4,6-trinitrotoluene (TNT). However, the viscosity of molten DNP is considerably greater compared with that of TNT, thus, requiring the viscosity of DNP-based melt-cast explosive suspensions to be minimized. In this paper, the apparent viscosity of a DNP/HMX (cyclotetramethylenetetranitramine) melt-cast explosive suspension is measured using a Haake Mars III rheometer.
View Article and Find Full Text PDFMaterials (Basel)
August 2022
State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, China.
When describing the relation between the flow stress and plastic strain of a material under a wide range of strain rates and temperatures, the original Johnson-Cook model generally requires a complicated modification, resulting in a loss of simplicity and clear physical interpretation. In this paper, without modification, the original Johnson-Cook model was calibrated separately for the static and dynamic compression of a DNAN-based melt-cast explosive. The stress-strain curves for static and dynamic compression of this explosive were experimentally measured with a universal testing machine and a split-Hopkinson pressure bar, respectively.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!