We report on a non-destructive method for evaluating fluorescence emission from fluorophores placed upon engineered photonic structures. Our method utilizes re-usable, fluorescent thin film coated polydimethylsiloxane (PDMS) stamps. We harness the inherent characteristics of PDMS slabs; their ability to form conformal contact through van der Waals interactions in bringing the coated fluorescent layer on PDMS into close proximity of the photonic structure of interest. Fluorescence measurements are performed using the PDMS slab while in conformal contact with the test structure, allowing one to re-use these stamps for reliable evaluation over multiple samples. Transfer of the fluorescent film from the PDMS to the test structures is mitigated by the use of appropriate cross linkers that covalently bond the fluorescent film to the PDMS surface. To demonstrate the application potential of this approach, we report on the evaluation of fluorescence emission modulation from patterned nanoporous thin films, which are particularly challenging to evaluate using traditional approaches, and from plasmonic gratings supporting metal enhanced fluorescence. Comparison with traditional evaluation approaches has been made to showcase the superiority of the reported technique.
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http://dx.doi.org/10.1039/c7an01010a | DOI Listing |
Micron
February 2025
Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, PA 19104, USA. Electronic address:
Two-dimensional (2D) materials have many applications ranging from heterostructure electronics to nanofluidics and quantum technology. In order to effectively utilize 2D materials towards these ends, they must be transferred and integrated into complex device geometries. In this report, we investigate two conventional methods for the transfer of 2D materials: viscoelastic stamping with polydimethylsiloxane (PDMS) and a heated transfer with poly bis-A carbonate (PC).
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Suzhou Key Laboratory of Novel Semiconductor-optoelectronics Materials and Devices, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China.
Transfer printing can pattern emissive colloidal quantum dot (CQD) arrays with ultrahigh pixel density. However, the most used pick-and-place method has difficulty in achieving high pattern fidelity. Here, we report that the regularly used single-composite stamps cannot combine a low deformation rate and conformal contact, leading to the challenge.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2024
Institute of Industrial Science, University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan.
Two-dimensional (2D) materials can be transferred onto substrates with various surface structures, opening up multiple functions and applications for 2D materials in the form of suspended membranes. In this paper, we present a method for transferring exfoliated 2D crystal flakes from SiO substrates onto patterned substrates using a poly(vinyl chloride) (PVC) layer mounted on a polydimethylsiloxane (PDMS) stamp structure. 2D crystal flakes can be transferred onto various patterned structures such as grooves, round holes, and periodic hole or groove patterns.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2024
Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, Florida 32611, United States.
The diffusion of uncured polydimethylsiloxane (PDMS) oligomers out of bulk PDMS elastomers is usually detrimental to many biomedical and microfluidic applications due to the inevitable contamination of the contacting fluids and substrates. Here, we transform this detrimental process into an enabling technology for achieving novel reconfigurable antireflection (AR) coatings, which are of great technological importance in the development of new nano-optical and optoelectronic applications. Self-assembled monolayer silica colloidal crystals are first used as sacrificial templates in fabricating nanoporous polymer AR coatings.
View Article and Find Full Text PDFNanoscale
October 2024
School of Chemistry and Chemical Engineering, Yantai University, Yantai 264006, P. R. China.
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