High performance electrochemical glucose sensor based on three-dimensional MoS/graphene aerogel.

J Colloid Interface Sci

Department of Chemical & Biomolecular Engineering, KAIST, 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea. Electronic address:

Published: November 2017

Two-dimensional (2D) nanosheets have been extensively explored as electrode materials for the development of high-performance electrochemical biosensors due to their unique structural characteristics. Nevertheless, 2D nanosheets suffer from sheet aggregation issues limiting the electrical conductivity of layered metal sulfides or hydroxides. Here, we report high-performance glucose biosensors based on a three-dimensional (3D) aerogel composed of interconnected 2D MoS and graphene sheet. 3D MoS/graphene aerogel (MGA) provides a large surface area for the effective immobilization of enzymes, and continuous framework of electrically conductive graphene sheets. Flow-injection amperometric evaluation of the glucose biosensor using a 3D MGA electrode exhibits a rapid response (∼4s), a linear detection range from 2 to 20mM, a sensitivity of 3.36μA/mM, and a low limit of detection of 0.29mM. Moreover, the interference response from oxidizable species, such as ascorbic acid, uric acid and dopamine is negligible at an operating potential of -0.45V.

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http://dx.doi.org/10.1016/j.jcis.2017.07.061DOI Listing

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