The surface functionalization will introduce additional functional groups on carbon dots (CDs) surface and then enrich the properties of CDs. Here, we show the various surface functionalized CDs (-COOH, -OH, -SH, -NH, etc, named as NS-CDs) were synthesized with fascinating features, including high quantum efficiency (38.9%), long-term stability and good biocompatibility. Notably, it can serve as multifunction fluorescent probe in sensing system, including label-free detections in hydrogen peroxide (HO) with a wide linear range (1.20 × 10 - 8.80 × 10M) and a low limit of detection (LOD, 1.00 × 10M); and glutathione, covering a concentration range of 2.00 × 10 - 1.00 × 10M and LOD of 1.00 × 10M. In addition, the NS-CDs as fluorescent probe could selectively detect metal ions (such as, Hg, 1.00 × 10 - 1.50 × 10M, 1.00 × 10M), antibiotics (tetracycline, 1.00 ×10 - 2.50 × 10M, 1.00 ×10M) and toxic pollutant (nitrobenzene, 5.00 × 10 to 1.00 × 10gL, 5.00 × 10gL) with wide linear range and satisfactory detection limits.
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http://dx.doi.org/10.1016/j.talanta.2017.05.067 | DOI Listing |
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