Direct arylation of inactivated benzene with aryl acyl peroxides toward biaryls.

Org Biomol Chem

School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, P. R. China.

Published: August 2017

A direct arylation of inactivated benzene with acyl peroxides was developed, affording biaryls in good to excellent yields. This transformation underwent a radical pathway under metal-free, base-free and additive-free conditions with good functional group compatibility.

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Source
http://dx.doi.org/10.1039/c7ob01564jDOI Listing

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