Water suspensions of cellulose nanofibres with xylan, xyloglucan and pectin were studied for foaming and structural properties as a new means for food structuring. The dispersions were analysed with rheological measurements, microscopy and optical coherence tomography. A combination of xylan with TEMPO-oxidized nanocellulose produced a mixture with well-dispersed air bubbles, while the addition of pectin improved the elastic modulus, hardness and toughness of the structures. A similar structure was observed with native nanocellulose, but the elastic modulus was not as high. Shear flow caused cellulose nanofibres to form plate-like flocs in the suspension that accumulated near bubble interfaces. This tendency could be affected by adding laccase to the dispersion, but the effect was opposite for native and TEMPO-oxidized nanocellulose. Nanocellulose type also influenced the interactions between nanofibers and other polysaccharides. For example, xyloglucan interacted strongly with TEMPO-oxidized nanocellulose (high storage modulus) but not with native nanocellulose.
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http://dx.doi.org/10.1016/j.carbpol.2017.06.028 | DOI Listing |
Int J Biol Macromol
January 2025
State Key Laboratory of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin 300457, PR China; Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Tianjin 300457, PR China; China Light Industry Key Laboratory of Papermaking and Biorefinery, Tianjin University of Science and Technology, Tianjin 300457, PR China. Electronic address:
Developing sensitive and reliable methods for detecting antibiotics in water solutions is essential for protecting public health and the environment. Here, we report a novel fluorescent film with superior mechanical properties and detection response to ciprofloxacin (CIP), achieved through the in-situ growth of europium-based metal-organic frameworks on TEMPO-oxidized cellulose nanofibrils (TOCNF). Firstly, Eu(III) and 2,6-pyridinedicarboxylic acid (DPA) served as precursors, and a simple self-assembly strategy was employed to grow the composite film material (Eu-DPA@TOCNF) in situ on TOCNF, which exhibited characteristic emission peaks.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Institute of Forest Science, Kangwon National University, Chuncheon 24341, Republic of Korea; Department of Forest Biomaterials Engineering, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon 24341, Republic of Korea. Electronic address:
Carbon dot-based nanozymes have gained significant attention, but their application in dye degradation remains limited due to low activity and challenges in recovery and reuse. To overcome these limitations, high peroxidase-active Co-doped carbon dots (CoCDs) with surface amines were synthesized via hydrothermal method and immobilized onto TEMPO-oxidized cellulose nanofibrils (TOCNF) aerogels using EDC/NHS coupling. For the first time, this study investigates the dye degradation efficiency of CDs nanozyme.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Department of Plastic and Cosmetic Surgery, Treatment Center of Burn and Trauma, Affiliated Hospital of Jiangnan University, Wuxi 214122, China. Electronic address:
The conversion of mechanical energy into electrical energy by triboelectric nanogenerators (TENG) has attracted attention in recent years, particularly in the field of wearable sensor. In this work, TEMPO-oxidized cellulose nanofibers (TOCNF) with carboxylate groups were compounded with MXene to serve as both the negative friction layer and the electrode in assembling a TENG with nylon. The synergistic effect between TOCNF and MXene was analyzed to disclose its influence on the performance of the as-prepared TENG.
View Article and Find Full Text PDFACS Sens
December 2024
Department of Chemical Science and Technologies, University of Rome Tor Vergata, Via della Ricerca Scientifica 1, Rome 00133, Italy.
Carbohydr Polym
January 2025
Department of Polymer Science and Engineering, University of Massachusetts, Amherst, Amherst, MA 01003, United States of America. Electronic address:
We report xerogels prepared from TEMPO-oxidized cellulose nanofiber (Ox-CNF) that have enhanced yield stresses and Young's Modulus (E) up to 15.4 MPa. The xerogels were highly porous (>95 %) and were measured by density determination, SEM, Brunauer-Emmet-Teller (BET) experiments, and microCT analysis.
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