A synergistic combination of nutrient reclamation from manure and resultant hydrochar upgradation by acid-supported hydrothermal carbonization.

Bioresour Technol

Biomass Energy Technology Research Center, Biogas Institute of Ministry of Agriculture, Chengdu 610041, PR China; Key Laboratory of Development and Application of Rural Renewable Energy, Biogas Institute of Ministry of Agriculture, Chengdu 610041, PR China.

Published: November 2017

Cattle manure was hydrothermally carbonized in acid solutions (0-2% HCl), then nutrient concentration in liquid product and physicochemical properties of hydrochar were characterized to investigate the effects of acid addition on hydrochar properties and nutrient recovery from manure. Results showed that hydrothermal carbonization (HTC) in 2% HCl extracted almost 100% and 63.38% of phosphorus and nitrogen, respectively; specifically, >90% of the extracted phosphorus was PO-P in liquid from HTC with acid addition, and increasing amount of extracted nitrogen was NH-N with increasing acid addition. Generally, higher heating value, surface area, total pore volume, fixed carbon, atomic ratios of H/C and O/C were increased in hydrochars from HTC with acid addition, while yield, volatile matter, contents of nitrogen, sulfur and oxygen of these hydrochars were decreased. These results indicated that HTC with acid addition could simultaneously facilitate nutrient recovery from manure and resulting hydrochar upgradation.

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http://dx.doi.org/10.1016/j.biortech.2017.07.016DOI Listing

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