AI Article Synopsis
- - The study involves the synthesis and characterization of chiral two-bladed complexes [Co(L)][BF] and [Zn(L)][BF], featuring a unique bidentate ligand L.
- - These complexes are created as homochiral species but exist in a racemic mixture due to a process called ligand self-sorting.
- - The individual enantiomers of the complexes can be distinguished in solution through the use of optically active anions.
Article Abstract
Chiral two bladed complexes of [Co(L)][BF] (1) and [Zn(L)][BF] (2) containing an atropoisomeric semi-rigid bidentate ligand L were synthesized and characterized. They are obtained as homochiral species but in a racemic mixture via a ligand self-sorting mechanism. These enantiomers can be differentiated in solution using optically active anions.
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| http://dx.doi.org/10.1039/c7dt01151b | DOI Listing |
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