HfS is one of the emerging transition metal dichalcogenides and is very promising for low-power nanoelectronics and high-sensitivity optoelectronic device applications. We studied the band structures of 1T-HfS with different thicknesses by first principles simulation, and the impact of different metal contacts to the HfS device performance has been experimentally studied. Back-gate and top-gate HfS field-effect transistors (FETs) were fabricated, and better electrical characteristics have been achieved with the FETs with the Ti/Au contact as compared with the Pt-contacted FETs. Thin layers of Pt and Ti/Au films were deposited on HfS flakes to investigate the metal/HfS interface by using scanning electron microscopy, atomic force microscopy, and Raman spectroscopy. A smoother Ti/Au film was formed on HfS, resulting in higher carrier injection and transport efficiency. The phonon behavior being dominated by the interface chemical bonding at the Ti/Au contact region has been confirmed with the more sensitive A phonon mode from the bilayer HfS.
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http://dx.doi.org/10.1021/acsami.7b06160 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
National University of Singapore, Chemistry, 3 Science Drive 3, 117543, Singapore, SINGAPORE.
Achieving high ionic conductivity and stable performance at low temperatures remains a significant challenge in sodium-metal batteries (SMBs). In this study, we propose a novel electrolyte design strategy that elucidates the solvation structure-function relationship within mixed solvent systems. A mixture of diglyme and 1,3-dioxolane was developed to optimize the solvation structure towards superior low-temperature electrolyte.
View Article and Find Full Text PDFObes Rev
January 2025
Inserm UMR 1256 Nutrition-Genetics-Environmental Risk Exposure (N-G-ERE), University of Lorraine, Nancy, France.
Limited literature addresses the association between pollution, stress, and obesity, and knowledge synthesis on the associations between these three topics has yet to be made. Two reviewers independently conducted a systematic review of MEDLINE, Embase, and Web of Science Core Collection databases to identify studies dealing with the effects of semi-volatile organic compounds, pesticides, conservatives, and heavy metals on the psychosocial stress response and adiposity in humans, animals, and cells. The quality of papers and risk assessment were evaluated with ToxRTool, BEES-C instrument score, SYRCLE's risk of bias tool, and CAMARADES checklist.
View Article and Find Full Text PDFActa Physiol (Oxf)
February 2025
Department of Biochemistry, Cell and Systems Biology, Institute of Systems, Molecular and Integrative Biology, Faculty of Health and Life Sciences, University of Liverpool, Liverpool, UK.
Aim: Long QT syndrome (LQTS) and catecholaminergic polymorphism ventricular tachycardia (CPVT) are inherited cardiac disorders often caused by mutations in ion channels. These arrhythmia syndromes have recently been associated with calmodulin (CaM) variants. Here, we investigate the impact of the arrhythmogenic variants D131E and Q135P on CaM's structure-function relationship.
View Article and Find Full Text PDFEnviron Geochem Health
January 2025
College of Resources and Environmental Engineering, Guizhou University, Guiyang, 550025, China.
The superposition of heavy metals (HMs) from multiple anthropogenic sources in geochemical anomaly areas makes it difficult to discriminate prime sources in atmospheric HMs. This study utilized a combination of microscopic features, positive matrix factorisation, and Pb isotope fingerprints to trace the main sources of HMs bound to total suspended particulates (TSP) at a pollution site (Msoshui: MS) and control site (Lushan: LS) in northwestern Guizhou. The results reveal that the concentrations of Cd, Pb, Cr, As, Cu, Ni, and Zn in the TSP of LS are 3.
View Article and Find Full Text PDFMol Biol Rep
January 2025
Plant Protection and Bimolecular Diagnosis Department, Arid Lands Cultivation Research Institute, City of Scientific Research and Technological Applications, New Borg El-Arab 21934, Alexandria, Egypt.
Background: Heavy metal contamination, particularly from lead (Pb), poses a significant threat to plant agriculture worldwide, adversely affecting growth, physiological functions, and yield. Signalling molecules such as calcium and salicylic acid are known to mitigate various stresses in plants, prompting this study to explore their interaction with Pb stress in wheat.
Methods: A pot experiment was conducted in which wheat grains were primed with either distilled water, 5 mM calcium (Ca), or 0.
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