We present a crystal engineering strategy to fine tune the pore chemistry and CH -storage performance of a family of isomorphic MOFs based upon PCN-14. These MOFs exhibit similar pore size, pore surface, and surface area (around 3000 m g ) and were prepared with the goal to enhance CH working capacity. [Cu (L2)(H O) ] (NJU-Bai 41: NJU-Bai for Nanjing University Bai's group), [Cu (L3)(H O) ] (NJU-Bai 42), and [Cu (L4)(DMF) ] (NJU-Bai 43) were prepared and we observed that the CH volumetric working capacity and volumetric uptake values are influenced by subtle changes in structure and chemistry. In particular, the CH working capacity of NJU-Bai 43 reaches 198 cm (STP: 273.15 K, 1 atm) cm at 298 K and 65 bar, which is amongst the highest reported for MOFs under these conditions and is much higher than the corresponding value for PCN-14 (157 cm (STP) cm ).
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/anie.201704974 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Service capacity and disability resource integration: A strategic survey of immigrant and refugee-serving agencies in Illinois.
Am J Community Psychol
January 2025
Illinois Department of Human Services (IDHS) Division of Vocational Rehabilitation Services, Illinois Department of Central Management and Triton College, Springfield, Illinois, USA.
Immigrants and refugees in the United States often face significant barriers in accessing social services, including mental health support, legal assistance, ESL or related education, housing, vocational training, workforce resources, transportation, and citizenship support. This article explores the strengths and challenges of community-based organizations welcoming centers (CBO WC) in Illinois that serve these populations, including people with disabilities, in culturally appropriate and inclusive ways. The Immigrant and Refugee-Led Capacity Development Network of Illinois, based at the University of Illinois Chicago, collaborated with the state's Office of Welcoming Centers to explore the service capacities of 17 CBO grantees.
View Article and Find Full Text PDFRADAR-AD: assessment of multiple remote monitoring technologies for early detection of Alzheimer's disease.
Alzheimers Res Ther
January 2025
Fraunhofer Institute for Algorithms and Scientific Computing SCAI, Sankt Augustin, Germany.
Background: Alzheimer's disease (AD) is a progressive neurodegenerative disorder affecting millions worldwide, leading to cognitive and functional decline. Early detection and intervention are crucial for enhancing the quality of life of patients and their families. Remote Monitoring Technologies (RMTs) offer a promising solution for early detection by tracking changes in behavioral and cognitive functions, such as memory, language, and problem-solving skills.
View Article and Find Full Text PDFExploring the perspectives of early-stage postoperative glioblastoma patients and their caregivers on end-of-life care planning: An exploratory qualitative interview study.
Appl Nurs Res
February 2025
Institute of Community Health Care, College of Nursing, National Yang Ming Chiao Tung University, Taipei, Taiwan; Cicely Saunders Institute of Palliative Care, Policy and Rehabilitation, King's College London, UK. Electronic address:
Aim: Compare the convergent and divergent viewpoints of early-stage postoperative patients with glioblastoma and their caregivers on end-of-life care planning in Taiwan.
Background: Decision-making capacity in patients with glioblastoma may be compromised as disease progresses, making early future care planning essential to ensure that the provided care aligns with patients' goals. However, within many Asian cultures, the tendency to avoid discussions about death can lead patients to feel hesitant about addressing end-of-life care options.
Potential of carbon micro/nanofibers derived from lignocellulose biomass valorisation for CO adsorption: A review on decarbonization biotechnology for climate change solutions.
Int J Biol Macromol
January 2025
Desalination Technology Institute, King Abdulaziz City for Science and Technology, Riyadh 12354, Saudi Arabia.
Biomass, as a source of lignocellulose, can be valorized into carbon micro/nanofibers for adsorbing greenhouse gas (GHGs) emissions, especially CO. This article is derived from systematic evidence evaluation of published studies, presenting new, innovative, and systemic approaches to lignocellulose-based carbon micro/nanofiber studies. The review covers a general overview of carbon micro/nanofiber studies, mapping chronicles of the studies, carbon micro/nanofiber types for CO uptake, carbon micro/nanofibers fabrication and characterization, obtained carbonaceous material activation and performances, regulatory frameworks, and sustainability.
View Article and Find Full Text PDFExploiting agri-food residues for kombucha tea and bacterial cellulose production.
Int J Biol Macromol
January 2025
NBFC - National Biodiversity Future Center, 90133 Palermo, Italy; University of Naples Federico II, Department of Biology, Naples, Italy. Electronic address:
Bio-valorization of agri-food wastes lies in their possible conversion into fermented foodstuffs/beverages and/or biodegradable polymers such as bacterial cellulose. In this study, three different kombucha cultures were formulated using agri-food waste materials, citrus fruit residues and used coffee grounds, as alternative carbon and nitrogen sources, respectively. Over 21 days of fermentation, the kinetic profile was followed by monitoring cell number, pH variation, minerals, trace elements and production of bacterial cellulose.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!