Optically active phenylene-ethynylene dimers with pyridine groups based on a planar chiral 4,7,12,15-tetrasubstituted [2.2]paracyclophane were synthesized. The chiral conformation was controlled by pyridine-Ag(i) coordinations. After Ag(i) coordination, the resulting higher-ordered structure dramatically enhanced the signal intensity of circular dichroism (CD) and decreased that of circularly polarized luminescence (CPL).
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Front Neural Circuits
August 2024
Laboratory of Functional Brain Circuit Construction, Graduate School of Brain Science, Doshisha University, Kyotanabe, Japan.
Recent advances in human pluripotent stem cell (hPSC) technologies have prompted the emergence of new research fields and applications for human neurons and brain organoids. Brain organoids have gained attention as an model system that recapitulates the higher structure, cellular diversity and function of the brain to explore brain development, disease modeling, drug screening, and regenerative medicine. This progress has been accelerated by abundant interactions of brain organoid technology with various research fields.
View Article and Find Full Text PDFBioorg Med Chem Lett
April 2024
Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario K1S 5B6, Canada; Institute of Biochemistry, Carleton University, 1125 Colonel By Drive, Ottawa, Ontario K1S 5B6, Canada. Electronic address:
Amphiphilic peptide sequences are conducive to secondary structures that self-assemble into higher-ordered peptide nanostructures. A select set of amphiphilic polycationic peptides displayed stable helical-coiled structures that self-assembled into peptide nanofibers. The progression of peptide fibril formation revealed short protofibrils that extended into thin filaments and into an entangled network of nanofibers over an extended (5 days) incubation period.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2024
Applied Chemistry Program, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-4-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8527, Japan.
Thiazole, as a family of five-membered heteroaromatic rings, is an interesting building unit that can play a role in coplanarizing the backbone as well as deepening the HOMO energy level, which is beneficial for the design of π-conjugated polymers for the photoactive materials in organic photovoltaics (OPVs). Here, we designed and synthesized π-conjugated polymers with simple chemical structures, which consist of 2,2'-bithiazole or 5,5'-bithiazole and alkylthiophenes as the polymer backbone. In fact, the polymers can be easily synthesized in much fewer steps compared to the typical high-performance polymers based on fused heteroaromatic rings.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2024
Department of Chemistry Indian Institute of Science, Education and Research Bhopal, Bhopal Bypass Road, Bhauri, Bhopal, 462066 Madhya Pradesh, India.
The real-time monitoring of the stepwise growth process of the molecular crystal reveals a conclusive understanding of the morphological evolution, which otherwise remains elusive during the conventional crystallization processes. Herein, we report the crystallization of silver nanoclusters (AgNCs) with special emphasis on their differential growth and multicolor emissive properties. A subtle variation of the methanol (MeOH) proportion in the reaction mixture induces the differential growth of these AgNCs, and thereby, a dramatic modulation in their optical properties was observed.
View Article and Find Full Text PDFJ Mater Chem B
December 2023
Department of Bioproducts and Biosystems, School of Chemical Engineering, Aalto University, Kemistintie 1, Finland.
Morpheeins are proteins that adapt their morphology and function to the environment. Therefore, their use in nanotechnology opens up the bottom-up preparation of anisotropic metamaterials, based on the sequential use of different stimuli. A prominent member of this family of proteins is peroxiredoxins (Prx), with dual peroxidase and chaperone function, depending on the pH of the media.
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