A new perovskite solar cell (PSC) structure with a functionalized interface between perovskite and a hole transport material has been proposed in this report. The short circuit current density of PSC was notably enhanced with the novel architecture (with an increase of 8.7%), and a power conversion efficiency (PCE) of 16.93% was achieved. With the increased perovskite/hole conductor interface, hysteresis suppression was observed. The advantages of this structure in light-harvesting efficiency, trap density, and carrier separation rate were proved by various characterization and analysis studies. It is noteworthy that a PCE of 14.67% was achieved with poly(3-hexyl-thiophene), which to our knowledge is the highest performing PSC based on this material.
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http://dx.doi.org/10.1021/acsami.7b03666 | DOI Listing |
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