PET-modified red mud as catalysts for oxidative desulfurization reactions.

J Environ Sci (China)

Department of Chemistry, Federal University of Minas Gerais, Av. Antônio Carlos 6627, Campus Pampulha, 31270-901, BH-MG, Brazil. Electronic address:

Published: July 2017

This work describes the synthesis of catalysts based on red mud/polyethylene terephthalate (PET) composites and their subsequent heat treatment under N atmosphere. The materials were characterized by scanning electron microscopy (SEM), temperature programmed reduction (TPR), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric (TG) analysis and N adsorption/desorption. The catalysts were evaluated in the oxidative desulfurization reaction of dibenzothiophene (DBT) in a biphasic system. The results indicated that the PET impregnation on red mud increased the affinity of the catalyst with the nonpolar phase (fuel), in which the contaminant was dissolved, allowing a higher conversion (up to 80%) and selectivity to the corresponding dibenzothiophene sulfone. The sulfone compound is more polar than DBT and diffused into the polar solvent as indicated by the data obtained via gas chromatography-mass spectrometry (GC-MS).

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http://dx.doi.org/10.1016/j.jes.2017.01.011DOI Listing

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