1,3-Bis{()-[4-(di-methyl-amino)-benzyl-idene]amino}-propan-2-ol: chain structure formation an O-H⋯N hydrogen bond.

Acta Crystallogr E Crystallogr Commun

Institut für Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Max-von-Laue-Str. 7, 60438 Frankfurt/Main, Germany.

Published: June 2017

The asymmetric unit of the title compound, CHNO, consists of two unique mol-ecules linked by an O-H⋯N hydrogen bond. The conformation of both C=N bonds is and the azomethine functional groups lie close to the plane of their associated benzene rings in each of the independent mol-ecules. The dihedral angles between the two benzene rings are 83.14 (4) and 75.45 (4)°. The plane of the one of the N(CH) units is twisted away from the benzene ring by 18.8 (2)°, indicating loss of conjugation between the lone electron pair and the benzene ring. In the crystal structure, O-H⋯N hydrogen bonds together with C-H⋯O hydrogen bonds link neighbouring supra-molecular dimers into a three-dimensional network.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5458298PMC
http://dx.doi.org/10.1107/S2056989017006429DOI Listing

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