We study the swelling and shrinking behavior of core-shell microgels adsorbed on silicon wafers. In these systems, the core is made of cross-linked poly(N-isopropylmethacrylamide) and the shell consists of cross-linked poly(N-n-propylacrylamide). In suspension, these particles exhibit an extended linear swelling behavior in the temperature interval between the lower critical solution temperatures of the two polymers. Using ellipsometry and atomic force microscopy, we show that this linear response is also observed in the adsorbed state.
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http://dx.doi.org/10.1021/acs.langmuir.7b01199 | DOI Listing |
Langmuir
May 2024
Physics Department, Lomonosov Moscow State University, Leninskie gory 1-2, 119991 Moscow, Russian Federation.
Emulsions have become a crucial product form in various industries in modern times. Expanding the class of substances used to stabilize emulsions can improve their stability or introduce new properties. Particularly, the use of stimuli-responsive microgels makes it possible to create "smart" emulsions whose stability can be controlled by changing any of the specified stimuli.
View Article and Find Full Text PDFJ Colloid Interface Sci
July 2023
Department of Materials Science & Engineering, Indian Institute of Technology Delhi, New Delhi 110016, India. Electronic address:
The present study focuses on creating an antimicrobial and biocatalytic smart gating membrane by synthesizing unique core-shell microgels. The core-shell microgels are synthesized by grafting short chains of poly(ethylenimine) (PEI) onto a poly((N-isopropyl acrylamide)-co-glycidyl methacrylate)) (P(NIPAm-co-GMA)) core. Subsequently, the produced microgels are utilized as a substrate for synthesizing and stabilizing silver nanoparticles (Ag NPs) through an in-situ approach.
View Article and Find Full Text PDFLangmuir
July 2017
Department of Physical and Biophysical Chemistry, Bielefeld University , Universitaetsstrasse 25, 33615 Bielefeld, Germany.
We study the swelling and shrinking behavior of core-shell microgels adsorbed on silicon wafers. In these systems, the core is made of cross-linked poly(N-isopropylmethacrylamide) and the shell consists of cross-linked poly(N-n-propylacrylamide). In suspension, these particles exhibit an extended linear swelling behavior in the temperature interval between the lower critical solution temperatures of the two polymers.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2014
Leibniz-Institut für Polymerforschung Dresden e.V. , Hohe Straße 6, 01069 Dresden, Germany.
Thermoresponsive core-shell microgels with degradable core are synthesized via surfactant based free radical polymerization using N,N'-(1,2-dihydroxy-ethylene)bis(acrylamide) (DHEA) as a cross-linker for core preparation. The 1,2-glycol bond present in DHEA is susceptible to NaIO4 solution, and thus, the structure can be cleaved off resulting in hollow microgel. Ultrathin membranes are prepared by suction filtration of a dilute suspension of core-shell microgels over a sacrificial layer of Cd(OH)2 nanostrand coated on track etched membrane.
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