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Cation-Driven Self-Assembly of a Gold(I)-Based Metallo-Tweezer. | LitMetric

Cation-Driven Self-Assembly of a Gold(I)-Based Metallo-Tweezer.

Angew Chem Int Ed Engl

Institute of Advanced Materials (INAM), Universitat Jaume I, Av. Vicente Sos Baynat s/n, 12071, Castellón, Spain.

Published: August 2017

A combination of self-complementary π-π-stacking interactions and metallophilic interactions triggered the self-assembly of a new digold(I) metallo-tweezer in the presence of several types of M ions. Titrations by fluorescence spectroscopy enabled the determination of the association constants of the resulting inclusion duplex complexes.

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Source
http://dx.doi.org/10.1002/anie.201704359DOI Listing

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