We measured the Rapini-Papoular polar anchoring strength coefficient W for 4^{'}-pentyl-4-cyanobiphenyl (5CB) on alignment layers formed by the reactive mesogen photopolymers RM 257, RM 82, and RM 84 [4,4^{'}-bis(acryloyl)biphenyl] (by Merck). These materials are commonly used for the photostabilization of the liquid crystal (LC) director in the bulk as well as at the surface of the LC layer via the formation of a loose polymer network that captures the director orientation. We developed a method of fabrication of alignment layers from these polymers, and estimated W from the measurements of the optical retardation as a function of applied voltage in uniformly aligned cells. We found that RM 257 yielded W of about 6×10^{-4}J/m^{2}, whereas RM 82 and RM 84 provided anchoring strengths of about 2×10^{-4} and 4×10^{-4}J/m^{2}, respectively. Subsequent heating of the sample either destroyed the alignment layer, or substantially decreased W to about 1×10^{-4}J/m^{2}, which was comparable to the anchoring strength of weakly rubbed commercial polyimides.
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http://dx.doi.org/10.1103/PhysRevE.95.052706 | DOI Listing |
Int J Biol Macromol
January 2025
Anhui Key Laboratory of Advanced Building Materials, Anhui Jianzhu University, Hefei 230022, China.
A styrene-glycidylmethacrylate-1-allyl-3-vinylimidazole epoxy functionalized ionomer (EFI) was synthesized, and the EFI and carbon nanotubes (CNTs) were co-introduced into poly(lactide)/poly(butylene-adipate-co-terephtalate) (PLA/PBAT) blends to fabricate high performance composites with excellent mechanical properties, fatigue-resistance and dielectric properties. It is revealed that EFI can improve the interaction force between PLA and PBAT by inducing the interfacial crosslink reaction, thereby improving the melt strength of the samples. EFI can also refine the dispersion of CNT in the composites owing to the non-covalent force between EFI and CNT, promote the formation of filler network inside composites, which is demonstrated by DMA and rheological test results.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Key Laboratory of Advanced Energy Materials Chemistry, College of Chemistry, Weijin Road 94, 300071, Tianjin, CHINA.
Arthrosc Tech
December 2024
Department of Orthopaedic Surgery, University of California Irvine, Orange, California, U.S.A.
Acute, traumatic distal biceps tendon ruptures are a common injury in the middle-aged athletic male population, with direct anatomic surgical repair being the most effective technique to restore maximal strength. Multiple techniques for distal biceps tendon repair have been described, including single- or dual-incision approaches and tendon fixation with cortical buttons, interference screws, suture anchors, and transosseous sutures. In this Technical Note, we demonstrate an anatomic distal biceps tendon repair technique with a single-incision approach using 2 all-suture cortical buttons.
View Article and Find Full Text PDFAm J Sports Med
January 2025
Mayo Clinic Arizona Department of Orthopedic Surgery, Phoenix, Arizona, USA.
Background: The Latarjet and other bony augmentation procedures are commonly used to treat anterior shoulder instability in the setting of significant glenoid bone loss. Although several fixation strategies have been reported, the biomechanical strength of these techniques remains poorly understood.
Purpose: To perform a systematic review of the biomechanical strength of glenoid bony augmentation procedures for anterior shoulder instability.
J Colloid Interface Sci
January 2025
Key Laboratory of Photonic and Electronic Bandgap Materials, Ministry of Education, School of Physics and Electronic Engineering, College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China. Electronic address:
Electrocatalytic NO reduction (NORR) to NH represents a promising approach for converting hazardous NO waste gases into high-value NH products under ambient conditions. However, exploring stable, low-cost, and highly efficient catalysts to enhance the NO-to-NH conversion process remains a significant challenge. Herein, through systematic computational studies based on density functional theory (DFT), we rationally designed transition metal triatomic cluster supported on graphdiyne (TM/GDY) as potential single-cluster catalysts for high-performance NORR.
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