Zinc-Zinc Double Bonds: A Theoretical Study.

Angew Chem Int Ed Engl

Department de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Institut de Química Teòrica i Computacional, Universitat de Barcelona, Martí i Franquès, 1-11, 08028, Barcelona, Spain.

Published: August 2017

While double bonds are known for transition metals of Groups 9 and 10 as well as for boron and p-block elements of Groups 14-16, Zn sits in a small region of the periodic table with no well-characterized double bonds. A qualitative reasoning indicates that zero-valent zinc has the potential to form Zn=Zn double bonds. A computational study in search for complexes that might showcase this new bond type is presented here.

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Source
http://dx.doi.org/10.1002/anie.201702171DOI Listing

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