Recent progress in synchrotron-based frequency-domain Fourier-transform THz-EPR.

J Magn Reson

Berlin Joint EPR Lab, Institute for Nanospectroscopy, Helmholtz-Zentrum Berlin für Materialien und Energie, Kekuléstraβe 5, 12489 Berlin, Germany. Electronic address:

Published: July 2017

We describe frequency-domain Fourier-transform THz-EPR as a method to assign spin-coupling parameters of high-spin (S>1/2) systems with very large zero-field splittings. The instrumental foundations of synchrotron-based FD-FT THz-EPR are presented, alongside with a discussion of frequency-domain EPR simulation routines. The capabilities of this approach is demonstrated for selected mono- and multinuclear HS systems. Finally, we discuss remaining challenges and give an outlook on the future prospects of the technique.

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http://dx.doi.org/10.1016/j.jmr.2017.04.001DOI Listing

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