Porous nanostructured materials are demonstrated to be very promising in catalysis due to their well accessible active sites. Thermally stable metal-organic frameworks (MOFs) as hard templates are successfully utilized to afford porous metal oxides and subsequently metal sulfides by a nanocasting method. The resultant metal oxides/sulfides show considerable Brunauer-Emmett-Teller (BET) surface areas, by partially inheriting the pore character of MOF templates. Preliminary investigation on the obtained hierarchically porous CdS for water splitting, as a proof of concept, demonstrates its much higher activity than both corresponding bulk and nanosized counterparts, under visible light irradiation. Given the structural diversity and tailorability of MOFs, such synthetic approach may open an avenue to the synthesis of advanced porous materials for functional applications.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/smll.201700632 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Gelatins derived from aronia-supplemented fish diets: Structural effect and molecular simulation.
Int J Biol Macromol
January 2025
Department of Biotechnological Genetics, Institute of Science, Trakya University, Edirne, Turkey.
Fish gelatin, a sustainable substitute for mammalian gelatin, frequently exhibits weaker gel strength and thermal stability, limiting its industrial uses. This study investigated an in vivo method to improve functional characteristics by supplementing Nile tilapia diets with Aronia extract. The control diet (A0) contained no Aronia extract, while the remaining four diets consisted of commercial pelleted feed enriched with 250 mg/kg (A250), 500 mg/kg (A500), 750 mg/kg (A750), and 1000 mg/kg (A1000) of Aronia extract.
View Article and Find Full Text PDFHigher concentration of trehalose dihydrate stabilizes recombinant IgG1 under forced stress conditions.
J Pharm Sci
January 2025
Department of Chemical Engineering, Indian Institute of Technology Delhi. Electronic address:
Stability of complex biotherapeutics like monoclonal antibodies is paramount for their safe and efficacious use. Excipients are inactive ingredients that are added to the purified product so as to offer it a stable environment. Trehalose dihydrate is a non-reducing sugar that is commonly used as a stabilizing agent in biotherapeutic formulations under liquid and frozen states.
View Article and Find Full Text PDFPreparation, modification, characterization, and stability evaluation of 5-methyltetrahydrofolate liposomes.
Food Chem
January 2025
Department of Food Science and Technology, Jinan University, Guangzhou 510632, China. Electronic address:
As an essential B vitamin, folate participates in one‑carbon metabolism. The 5-methyltetrahydrofolate (5-MTHF) avoids the drawbacks associated with folic acid and native folylpolyglutamate folate in food, thereby emerging as a superior alternative to folate supplement. To enhance the stability and digestibility of 5-MTHF, nanoliposome (NL) was modified using a layer-by-layer self-assembly method with chitosan (CH) and pectin (P).
View Article and Find Full Text PDFSilk-Corn Zein Alloy Materials: Influence of Silk Types (Mori, Thai, Muga, Tussah, and Eri) on the Structure, Properties, and Functionality of Insect-Plant Protein Blends.
Int J Mol Sci
December 2024
Department of Physics and Astronomy, Rowan University, Glassboro, NJ 08028, USA.
Biocompatible materials fabricated from natural protein polymers are an attractive alternative to conventional petroleum-based plastics. They offer a green, sustainable fabrication method while also opening new applications in biomedical sciences. Available from several sources in the wild and on domestic farms, silk is a widely used biopolymer and one of the strongest natural materials.
View Article and Find Full Text PDFSynthesis and Antibacterial Evaluation of Chlorhexidine- and Triclosan-Impregnated Kaolinite Nanocomposites.
Materials (Basel)
January 2025
Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, Almaty 050040, Kazakhstan.
Clay minerals are actively used to obtain a bioactive composite. Kaolinite, as a representative of clay minerals, possesses unique properties essential for the creation of biocomposite materials. This mineral, characterized by its distinctive layered structure, is chemically inert, highly stable, thermally resistant, eco-friendly, biocompatible, and non-toxic.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!