A T-shaped Ni complex was synthesized using a rigid acridane-based pincer ligand to prepare a metalloradical center. Structural data displays a nickel ion is embedded in the plane of a PNP ligand. Having a sterically exposed half-filled dx2-y2 orbital, this three-coordinate Ni species reveals unique open-shell reactivity including the homolytic cleavage of various σ-bonds, such as H-H, N-N, and C-C.
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| http://dx.doi.org/10.1002/anie.201704487 | DOI Listing |
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