Field-scale forward and back diffusion through low-permeability zones.

J Contam Hydrol

Soil and Water Sciences Department, University of Florida, Gainesville, FL 32611, United States. Electronic address:

Published: July 2017

AI Article Synopsis

  • Understanding back diffusion of contaminants from low-permeability zones to aquifers is crucial for effective site management and remediation efforts.
  • The study introduces a three-stage classification of contaminant plume life cycles based on their origins: 1) aquifer source zone dissolution, 2) combined source zone dissolution and back diffusion, and 3) only back diffusion.
  • Data from multiple field sites helped identify distinctive concentration profiles, allowing for the development of analytical models that can assist site managers in selecting appropriate remediation strategies based on the contamination stage and permeability zones.

Article Abstract

Understanding the effects of back diffusion of groundwater contaminants from low-permeability zones to aquifers is critical to making site management decisions related to remedial actions. Here, we combine aquifer and aquitard data to develop recommended site characterization strategies using a three-stage classification of plume life cycle based on the solute origins: aquifer source zone dissolution, source zone dissolution combined with back diffusion from an aquitard, and only back diffusion. We use measured aquitard concentration profile data from three field sites to identify signature shapes that are characteristic of these three stages. We find good fits to the measured data with analytical solutions that include the effects of advection and forward and back diffusion through low-permeability zones, and linearly and exponentially decreasing flux resulting from source dissolution in the aquifer. Aquifer contaminant time series data at monitoring wells from a mature site were well described using analytical solutions representing the combined case of source zone and back diffusion, while data from a site where the source had been isolated were well described solely by back diffusion. The modeling approach presented in this study is designed to enable site managers to implement appropriate remediation technologies at a proper timing for high- and low-permeability zones, considering estimated plume life cycle.

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http://dx.doi.org/10.1016/j.jconhyd.2017.05.001DOI Listing

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