Odd-Electron Bonds.

Chemphyschem

Computer-Chemie-Centrum, Department of Chemistry and Pharmacy, Friedrich-Alexander-University of Erlangen-Nuernberg, Nägelsbachstr. 25, 91052, Erlangen, Germany.

Published: October 2017

The history and theory of one- and three-electron bonds are presented and discussed. It is shown that the dependence of the odd-electron bond energy on the difference in ionization potentials of the bonding partners must be corrected to include the ion-pairing energy for neutral odd-electron bonded complexes.

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Source
http://dx.doi.org/10.1002/cphc.201700417DOI Listing

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