Directed growth of graphene nanomesh in purified argon via chemical vapor deposition.

Nanotechnology

Key Laboratory of Advanced Micro/Nano Functional Materials, Department of Physics and Electronic Engineering, Xinyang Normal University, Xinyang 464000, People's Republic of China. Energy-Saving Building Materials Innovative Collaboration Center, Xinyang Normal University, Xinyang 464000, People's Republic of China. National Laboratory of Solid State Microstructures, Department of Physics, Nanjing University, Nanjing 210093, People's Republic of China.

Published: June 2017

AI Article Synopsis

  • Graphene nanomeshes (GNMs) are innovative structures with adjustable properties that could enhance future technology in electronics, photonics, and energy applications.
  • Research focused on how argon (Ar) impacts the creation of GNMs, affecting their density and shape over different growth periods.
  • Advanced imaging techniques confirmed GNMs' hexagonal structure and highlighted the importance of copper oxide nanoparticles formed during oxidization, suggesting they are crucial for the GNM growth process in purified Ar.

Article Abstract

Graphene nanomeshes (GNMs), new graphene nanostructures with tunable bandgaps, are potential building blocks for future electronic or photonic devices, and energy storage and conversion materials. In previous works, GNMs have been successfully prepared on Cu foils by the H etching effect. In this paper, we investigated the effect of Ar on the preparation of GNMs, and how the mean density and shape of them vary with growth time. In addition, scanning electron microscopy (SEM) and high resolution transmission electron microscopy (TEM) revealed the typical hexagonal structure of GNM. Atomic force microscopy (AFM) and x-ray photoelectron spectroscopy (XPS) indicated that large copper oxide nanoparticles produced by oxidization in purified Ar can play an essential catalytic role in preparing GNMs. Then, we exhibited the key reaction details for each growth process and proposed a growth mechanism of GNMs in purified Ar.

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Source
http://dx.doi.org/10.1088/1361-6528/aa7044DOI Listing

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