Deprotonated meso-hydroxyporphyrin as a stable π-electronic anion: the building unit of an ion-pairing assembly.

Dalton Trans

Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu 525-8577, Japan.

Published: July 2017

The Ni complex of 5-hydroxy-10,15,20-tris(pentafluorophenyl)-porphyrin was synthesized as the precursor of a negatively charged π-electronic system. Deprotonation, which was examined through UV/vis and H NMR spectra, provided an anionic species as the building unit of an ion-pairing assembly in combination with an aliphatic cation.

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http://dx.doi.org/10.1039/c7dt01635bDOI Listing

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