A paramagnetic W alkyne complex bearing free terminal diphenylphosphino groups at the side-on coordinated alkyne was synthesized using a stepwise template strategy. This moderately stable metal supported open shell diphosphine shows an unprecedented spontaneous splitting of nitric oxide providing a W-η-C{P(NH)Ph}{P(O)Ph} complex featuring an amino phosphonium and a phosphine oxide substituent.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c7cc02114c | DOI Listing |
Publication Analysis
Top Keywords
open shell
8
shell diphosphine
8
synthesis activation
4
activation potential
4
potential open
4
diphosphine paramagnetic
4
paramagnetic alkyne
4
alkyne complex
4
complex bearing
4
bearing free
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!