Controlled oxidation of palladium nanoparticles provided high-valent Pd oxo-clusters which efficiently promote directed C-H halogenation reactions. In addition, palladium nanoparticles can undergo changes in oxidation states to provide both high-valent Pd and low-valent Pd species within one system, and thus a tandem reaction of C-H halogenation and cross-coupling (C-N, C-C, and C-S bond formation) was successfully established.
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| http://dx.doi.org/10.1002/anie.201700301 | DOI Listing |
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