Ionic liquid/HO-mediated synthesis of mesoporous organic polymers and their application in methylation of amines.

Chem Commun (Camb)

Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Published: May 2017

Mesoporous Tröger's base-functionalized polymers (Meso-TBPs) were prepared using a sulfonic acid group functionalized ionic liquid/HO system, with surface areas up to 431 m g and pore sizes of 3-15 nm. Ir(ii) coordinated Meso-TBPs exhibited extraordinary catalytic performance in the N-methylation of amines using methanol.

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Source
http://dx.doi.org/10.1039/c7cc01910fDOI Listing

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