Palladium-catalyzed remote sp-sp coupling reaction of chloromethylarenes with allyltrimethoxysilane is described in this work. The allylation reaction regioselectively occurred on the para-positions of 1-(chloromethyl)naphthalenes and benzyl chlorides to form new C(sp)-C(sp) bonds. The reaction proceeds smoothly under mild conditions to produce allyl arenes in moderate to excellent yields.
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| http://dx.doi.org/10.1021/acs.joc.7b00678 | DOI Listing |
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