Polycyclic compounds containing a six-membered silacycle are important. However, we have limited knowledge of the nature of these six-membered silacycles because methodologies for their synthesis remain under-developed. Here, we have developed a one-pot enyne metathesis/Diels-Alder/oxidation methodology for the synthesis of six-membered silacycles. Some of these compounds are novel fluorophores.
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Ruthenium-Catalyzed Sequential Hydrosilylation/Dehydrogenation and C-H Silylation: Synthesis of Six-Membered Indole Silacycles and Pyrrole Silyl Ether Cycles.
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Department of Applied Chemistry, School of Engineering, The University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo 153-8505, Japan.
An Fe(II) bromide complex supported by a bidentate phosphine ligand and an η(C)-coordinated six-membered silacycle-bridged biphenyl-based ligand is converted upon reduction into an Fe(I) complex in which the hapticity of the silacycle-based ligand increases from η to η.
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Department of Applied Chemistry, School of Engineering Science, and Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan.
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Beilstein J Org Chem
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