Observation of dynamic atom-atom correlation in liquid helium in real space.

Nat Commun

Shull Wollan Center-Joint-Institute for Neutron Sciences, Oak Ridge National Laboratory and University of Tennessee, Oak Ridge, Tennessee 37831, USA.

Published: May 2017

Liquid He becomes superfluid and flows without resistance below temperature 2.17 K. Superfluidity has been a subject of intense studies and notable advances were made in elucidating the phenomenon by experiment and theory. Nevertheless, details of the microscopic state, including dynamic atom-atom correlations in the superfluid state, are not fully understood. Here using a technique of neutron dynamic pair-density function (DPDF) analysis we show that He atoms in the Bose-Einstein condensate have environment significantly different from uncondensed atoms, with the interatomic distance larger than the average by about 10%, whereas the average structure changes little through the superfluid transition. DPDF peak not seen in the snap-shot pair-density function is found at 2.3 Å, and is interpreted in terms of atomic tunnelling. The real space picture of dynamic atom-atom correlations presented here reveal characteristics of atomic dynamics not recognized so far, compelling yet another look at the phenomenon.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5418607PMC
http://dx.doi.org/10.1038/ncomms15294DOI Listing

Publication Analysis

Top Keywords

dynamic atom-atom
12
real space
8
atom-atom correlations
8
pair-density function
8
observation dynamic
4
atom-atom correlation
4
correlation liquid
4
liquid helium
4
helium real
4
space liquid
4

Similar Publications

Binary ionic melts formed by a protic ionic liquid (PIL) 1,2,4-triazolium methanesulfonate ([TAZ][MS]) dissolved in methanesulfonic acid are studied as non-stoichiometric electrolytes. The composition-driven structure-property relationship of methanesulfonic acid is explored at varying molar fraction ratios from 0/100 to 10/90, 20/80, and 30/70 by the addition of 1,2,4-triazolium methanesulfonate [TAZ][MS] IL. To unveil molecular characteristics of these mixtures of [TAZ][MS] PIL and CHSOH, we performed classical molecular dynamics simulations at varying temperatures from 293 to 303, 363, and 423 K.

View Article and Find Full Text PDF

Using a recent polarizable model for water (the BK3 model), we explore the collective dynamic modes in liquid water by molecular dynamics (MD) simulation. The dynamic structure factor and the longitudinal and transverse current correlation spectral densities are computed over the whole frequency range below intramolecular excitations. MD results of atom-atom partial correlation functions are fitted using the Generalized Collective Modes (GCMs) model, involving relaxing modes occurring in the longitudinal component and propagating modes occurring in both components.

View Article and Find Full Text PDF

The influence of charge ordering in the microscopic structure of monohydroxy alcohols.

J Phys Condens Matter

April 2024

Department of Physics, Faculty of Science, University of Split, Rudjera Boškovića 33, 21000 Split, Croatia.

While radiation scattering data provides insight inside the microstructure of liquids, the Debye relation relating the scattering intensity() to the atom-atom structure factorsSab(k)shows that, ultimately, it is these individual structure correlation functions which contain the relevant information about the micro-structure. However, these quantities are not observables, except in few cases where one can invert the Debye relation to obtain the structure functions. In the majority of other cases, the need for model dependent computer simulations is unavoidable.

View Article and Find Full Text PDF
Article Synopsis
  • The three-body recombination reaction is crucial in chemical physics, involving a reaction that creates a new molecule from three particles.
  • The Python 3-Body Recombination program computes atomic three-body recombination rate coefficients using a classical trajectory method in a higher-dimensional framework.
  • The software has been tested against various experimental scenarios, demonstrating reliable predictions and improved performance through parallelization.
View Article and Find Full Text PDF

On the role of non-additive interactions in three-body recombination.

Phys Chem Chem Phys

February 2024

Department of Physics of Astronomy, Stony Brook University, Stony Brook 11794, USA.

Non-additive forces are a cornerstone of molecular spectroscopy and reaction dynamics. However, the relevance of non-additive forces in three-body recombination remains largely unexplored. In this work, we present a global study on the impact of non-additive interactions in three-body recombination: atom-atom-atom and ion-atom-atom.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!