We demonstrate enhanced absorption in solar cells and enhanced light emission in OLEDs by light interaction with a periodically structured microlens array. We simulate n-i-p perovskite solar cells with a microlens at the air-glass interface, with rigorous scattering matrix simulations. The microlens focuses light in nanoscale regions within the absorber layer enhancing the solar cell. Optimal period of ~700 nm and microlens height of ~800-1000 nm, provides absorption (photocurrent) enhancement of 6% (6.3%). An external polymer microlens array on the air-glass side of the OLED generates experimental and theoretical enhancements >100%, by outcoupling trapped modes in the glass substrate.
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http://dx.doi.org/10.1364/OE.25.010704 | DOI Listing |
Nat Commun
January 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, PR China.
All-perovskite tandem solar cells (APTSCs) offer the potential to surpass the Shockley-Queisser limit of single-junction solar cells at low cost. However, high-performance APTSCs contain unstable methylammonium (MA) cation in the tin-lead (Sn-Pb) narrow bandgap subcells. Currently, MA-free Sn-Pb perovskite solar cells (PSCs) show lower performance compared with their MA-containing counterparts.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2025
Department of Physics, Liaoning University, Shenyang 110036, Liaoning, China. Electronic address:
To investigate the influence of the position and quantity of thiophene or acetylene groups on the photoelectric properties of dye-sensitized solar cells (DSSCs), density functional theory (DFT) were employed to simulate five zinc porphyrin dye molecules (T-3, T-3-D, T-3-A, T-3-AD, and T-3-ace). The optimized geometry indicated that T-3-ace possessed superior planar properties, attributed to incorporating the acetylene groups, facilitating the charge transfer process. The lower lowest unoccupied molecular orbital (LUMO) energy levels of T-3-ace and T-3-D suggested that introducing thiophene or acetylene groups on the donor side enhanced the electron absorption capability of the dyes.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physics, Indian Institute of Technology Roorkee, Roorkee, Uttarakhand, 247667, India.
This paper explores the development of an opto-thermal-electrical model for plasmonic Schottky solar cells (PSSCs) using a comprehensive multiphysics approach. We simulated the optical properties, power conversion efficiencies, and energy yield of PSSCs with varying nanoparticle (NP) configurations and sizes. Our spectral analysis focused on the absorption characteristics of these solar cells, examining systems sized 3 × 3, 5 × 5, and 7 × 7, with NP radii ranging from 10 to 150 nm.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Chemistry, University of California Berkeley, Berkeley, California 94720, United States.
Understanding charge transport in semiconductor quantum dot (QD) assemblies is important for developing the next generation of solar cells and light-harvesting devices based on QD technology. One of the key factors that governs the transport in such systems is related to the hybridization between the QDs. Recent experiments have successfully synthesized QD molecules, arrays, and assemblies by directly fusing the QDs, with enhanced hybridization leading to high carrier mobilities and coherent band-like electronic transport.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Physics, Chair for Functional Materials, TUM School of Natural Sciences, Technical University of Munich, James-Franck-Str. 1, 85748 Garching, Germany.
Solid additives have garnered significant attention due to their numerous advantages over liquid additives. This study explores the potential of the green-fluorescent conjugated polymer denoted Atums Green as a solid additive in green-solvent-based PBDB-TF-T1:BTP-4F-12 solar cells. Even tiny amounts of Atums Green doping significantly improve the device performance.
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