Fine-tuning of HUMs through pillar substitution can significantly enhance trace CO sorption performance and stability. The resulting materials, exemplified by the new material TIFSIX-3-Ni, [Ni(pyrazine)(TiF)], are shown through temperature programmed desorption experiments to remove trace quantities of CO from moist gas mixtures.

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http://dx.doi.org/10.1039/c7cc02289aDOI Listing

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