N-Heterocyclic carbene-stabilised arsinidene (AsH).

Chem Commun (Camb)

Institute of Inorganic and Analytical Chemistry, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.

Published: June 2017

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Article Abstract

N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe) with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)][AsCO] with imidazolium chlorides.

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http://dx.doi.org/10.1039/c7cc02628eDOI Listing

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