Serrated Au/Pd Core/Shell Nanowires with Jagged Edges for Boosting Liquid Fuel Electrooxidation.

ChemSusChem

State Key Lab of Chemo/Biosensing and Chemometrics, School of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, P. R. China.

Published: June 2017

Integration of 1D, core/shell, and jagged features into one entity may provide a promising avenue for further enhancing catalyst performance. However, designing such unique nanostructures is extremely challenging. Herein, 1D serrated Au/Pd core/shell nanowires (CSNWs) with jagged edges were produced simply by a one-pot, dual-capping-agent-assisted method involving co-reduction, galvanic replacement, directional coalescence of preformed nanoparticles, and site-selective epitaxial growth of Pd. Au/PdCSNWs, compared with the commercially available Pd/C, exhibited enhanced electrocatalytic performance towards liquid fuel oxidation because of the synergistic effect of the electronic structure and low-coordinated jagged edges.

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http://dx.doi.org/10.1002/cssc.201700602DOI Listing

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