AI Article Synopsis
- - A group of N-arylimide molecular balances was created to investigate and quantify the interactions between fluorine and aromatic compounds (F-π interactions).
- - The presence of fluorine led to stronger stabilizing effects with aromatic surfaces that have lower electron density.
- - F-π interactions are primarily driven by electrostatic forces and are found to be more potent than other types of halogen-π interactions.
Article Abstract
A series of N-arylimide molecular balances were designed to study and measure fluorine-aromatic (F-π) interactions. Fluorine substituents gave rise to increasingly more stabilizing interactions with more electron-deficient aromatic surfaces. The attractive F-π interaction is electrostatically driven and is stronger than other halogen-π interactions.
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| http://dx.doi.org/10.1002/anie.201702950 | DOI Listing |
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