Intramolecular atropselective aza Paternò-Büchi reaction involving atropisomeric enamide and imine functionalities under sensitized irradiation leads to azetidine products in good yield and selectivity (ee >96 %). A mechanistic model based on detailed photophysical and isomerization kinetic studies is provided that shed light into the reactivity of enamides leading to aza Paternò-Büchi reaction.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1002/anie.201702273 | DOI Listing |
Publication Analysis
Top Keywords
aza paternò-büchi
12
paternò-büchi reaction
12
realizing aza
4
reaction intramolecular
4
intramolecular atropselective
4
atropselective aza
4
reaction involving
4
involving atropisomeric
4
atropisomeric enamide
4
enamide imine
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!