The title complex, [PdCl(CHNO)]·2HO, was obtained by N-O bond cleavage of the oxa-diazo-line rings of the -[di-chlorido-bis-(2,5,5-trimethyl-5,6,7,7a-tetra-hydro-pyrrolo-[1,2-][1,2,4]oxa-diazole-)]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two -arranged chloride anions and a nitro-gen atom from each of the two neutral organic ligands. In the crystal, N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds link complex mol-ecules into double layers parallel to the plane.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382614 | PMC |
http://dx.doi.org/10.1107/S2056989017003929 | DOI Listing |
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