Crystal structure of -di-chloridobis-[-(5,5-di-methyl-4,5-di-hydro-3-pyrrol-2-yl-κ)acetamide]palladium(II) dihydrate.

Acta Crystallogr E Crystallogr Commun

Department of Chemistry, Rabigh College of Science and Arts, PO Box 344, King Abdulaziz University, Jeddah, Saudi Arabia.

Published: April 2017

The title complex, [PdCl(CHNO)]·2HO, was obtained by N-O bond cleavage of the oxa-diazo-line rings of the -[di-chlorido-bis-(2,5,5-trimethyl-5,6,7,7a-tetra-hydro-pyrrolo-[1,2-][1,2,4]oxa-diazole-)]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two -arranged chloride anions and a nitro-gen atom from each of the two neutral organic ligands. In the crystal, N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds link complex mol-ecules into double layers parallel to the plane.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382614PMC
http://dx.doi.org/10.1107/S2056989017003929DOI Listing

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