The dinuclear title compound, [In(CH)(CHS)] or [Me(2-MeCHS)In-μ-(2-MeCHS)InMe(2-MeCHS)], was prepared from the 1:2 reaction of MeIn and 2-MeCHSH in toluene. Its crystal structure exhibits a four-membered InS ring core bridging (2-MeCHS) groups. The dimeric units are further associated into a one-dimensional polymeric structure extending parallel to the axis inter-molecular In⋯S contacts. The In atoms are then in distorted trigonal-bipyramidal CS bonding environments.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC5382603 | PMC |
| http://dx.doi.org/10.1107/S2056989017003498 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Giant Seebeck Effect of Dibenzo[g,p]chrysene and its Derivatives: Deuteration and Substituent Effects and Relationship with Interlayer Distance.
Chem Asian J
January 2025
Kanagawa University, Department of Chemistry, JAPAN.
Thermoelectric properties of undoped crystals of dibenzo[g,p]chrysene (DBC), deuterated DBC (DBC-d16), and 2,10-dimethyl-DBC (DBC-Me2) have been studied to obtain some insights into the relationship between the structural parameters of materials and the giant Seebeck effect. X-ray crystallography showed one-dimensional columnar packing with the interlayer distances (d) for DBC-d16, DBC, and DBC-Me2 were 3.78 Å, 3.
View Article and Find Full Text PDFPbSiOCl and PbCaSiO: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response.
Inorg Chem
January 2025
School of Physics and Materials Science, Changji University, Changji 831100, People's Republic of China.
Finding novel efficient nonlinear optical materials with large second-order nonlinearity for the UV spectral range remains a formidable challenge, especially for silicate systems. Using a high-temperature solid reaction in a tight vacuum environment, two ultraviolet nonlinear optical materials with a moderate second harmonic generation (SHG) response have been created: PbSiOC and PbCaSiO. The SHG values they computed are roughly 2.
View Article and Find Full Text PDFSecupyritines A‒C, Three Natural Propellane Securinega Alkaloids: Structure Elucidation and Total Synthesis Based on Biogenetic Building Blocks.
Angew Chem Int Ed Engl
January 2025
Jinan University, State Key Laboratory of Bioactive Molecules and Druggability Assessment, CHINA.
Secupyritines A‒C are unique polycyclic Securinega alkaloids isolated from medicinal plant Flueggea suffruticosa. They feature a distinctive 6/6/6/5/6 fused pentacyclic ring system with a highly strained 2-oxa-6-aza[4.4.
View Article and Find Full Text PDFUranium Extraction from Seawater via Hydrogen Bond Porous Organic Cages.
J Am Chem Soc
January 2025
Key Laboratory of Polyoxometalate and Reticular Material Chemistry of the Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.
Uranium (U), a high-performing, low-emission energy source, is driving sustainable economic growth. Herein, we synthesized two crystalline phases (HPOC-α and β) by an unreported amidoxime organic cage used for uranium capture. The revealed crystal structures and uranium adsorption test showed that accessible functional groups were essential to uranyl ions sorption.
View Article and Find Full Text PDFControlling enzyme activity by mutagenesis and metal exchange to obtain crystal structures of stable substrate complexes of Class 3 l-asparaginase.
FEBS J
January 2025
Institute of Bioorganic Chemistry, Polish Academy of Sciences, Poznan, Poland.
Rhizobium etli is a nitrogen-fixing bacterium that encodes two l-asparaginases. The structure of the inducible R. etli asparaginase ReAV has been recently determined to reveal a protein with no similarity to known enzymes with l-asparaginase activity, but showing a curious resemblance to glutaminases and β-lactamases.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!