A series of diphosphoramidites has been synthetized with a piperazine, homopiperazine, and an acyclic 1,2-diamine unit in the backbone. New compounds were tested alongside related -acyl phosphoramidites as ligands in the Rh-catalyzed hydroformylation of -octenes to investigate their influence on the activity and regioselectivity. A subsequent study of their hydrolysis stability revealed that the most stable ligands induced the highest activity in the catalytic reaction.
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| http://dx.doi.org/10.1002/open.201600152 | DOI Listing |
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