Nitrogen and Phosphorus Harvesting from Human Urine Using a Stripping, Absorption, and Precipitation Process.

Environ Sci Technol

Department of Built Environment, School of Engineering, Aalto University, P.O. Box 14100 FI-00076 AALTO, Finland.

Published: May 2017

AI Article Synopsis

  • Human urine is a valuable resource for fertilizers due to its high nitrogen (N) and phosphorus (P) content, but its use faces challenges like transportation costs, odor, pathogens, and pharmaceutical residues.
  • A novel technique involving N stripping and P precipitation, using Ca(OH) to raise the pH of urine, successfully converts ammonium to ammonia gas and precipitates P as a Ca-P compound.
  • The study found that 85-99% of N and 99% of P can be extracted within 28-32 hours under specific conditions, allowing for potentially profitable mineral fertilizers from urine.

Article Abstract

Human urine contains significant amounts of N (nitrogen) and P (phosphorus); therefore it has been successfully used as fertilizer in different crops. But the use of urine as fertilizer has several constraints, such as, the high cost of transportation, an unpleasant smell, the risk of pathogens, and pharmaceutical residue. A combined and improved N stripping and P precipitation technique is used in this study. In this technique, Ca(OH) is used to increase the pH of urine which converts ammonium into ammonia gas and precipitate P as Ca-P compound. The ammonia gas is stripped and passed into the sulfuric acid where ammonium sulfate and hydrogen triammonium disulfate is formed. The experiment was performed using 700 mL of urine and the pH of the urine was increased above 12. Our results showed that 85-99% of N and 99% of P (w/w) can be harvested from urine in 28 h at 40 °C and in 32 h at 30 °C. The harvested N (13% N w/w) and P (1.5% P w/w) can be used as mineral fertilizer. The economic assessment of the technique showed that the extraction of N and P from 1 m of pure urine can make a profit of €2.25.

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Source
http://dx.doi.org/10.1021/acs.est.6b05402DOI Listing

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