Re-entrant microstructures exhibit excellent wetting stability under different pressure levels, but the underlying mechanism determined by wetting transition behavior at the microscale level remains unclear. We propose the "wetting chip" method for in situ assessment of the dynamic behavior of wetting transition in re-entrant microstructures. High sag and transverse depinning were observed in re-entrant microstructures. Analysis indicated that high sag and transverse depinning mainly influenced the stability of the structures. The threshold pressure and longevity of wetting transition were predicted and experimentally verified. The design criteria of wetting stability, including small geometry design, hydrophobic material selection, and sidewall condition, were also presented. The proposed method and model can be applied to different shapes and geometry microstructures to elucidate wetting stability.
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http://dx.doi.org/10.1021/acs.langmuir.7b00256 | DOI Listing |
Chemistry
January 2025
Shanghai Jiaotong University: Shanghai Jiao Tong University, College of Smart Energy, CHINA.
Transition-metal nitrides (TMNs) have garnered considerable attention for energy conversion applications owing to their exceptional electronic structures and high catalytic activities. However, the scarcity of active sites in TMNs impedes their large-scale application. This study describes the use of wetness impregnation and ionic-liquid methods to enhance the electrocatalytic efficiency of molybdenum nitride (MoN) atomic clusters finely dispersed on nitrogen-doped carbon (MoN@NC) substrates.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China.
The development of affordable, intelligent dual-separation technology is crucial for the treatment of oil-water mixtures. Pyridinium-based poly(ionic liquid)s (PILs), designed using molecular theory, exhibit unique switching wettability properties, making them ideal for use in both aqueous and oily environments. By prewetting the material's surface with water or oil, the targeted separation of these components becomes feasible.
View Article and Find Full Text PDFMicromachines (Basel)
November 2024
Queensland Micro- and Nanotechnology Centre, Griffith University, Nathan Campus, 170 Kessels Road, Brisbane, QLD 4111, Australia.
Surface wettability, the interaction between a liquid droplet and the surface it contacts, plays a key role in influencing droplet behavior and flow dynamics. There is a growing interest in designing surfaces with tailored wetting properties across diverse applications. Advanced fabrication techniques that create surfaces with unique wettability offer significant innovation potential.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Center of Super-Diamond and Advanced Films (COSDAF) and Department of Chemistry, City University of Hong Kong, Hong Kong SAR, 999077, P. R. China.
A new aggregation-induced emission (AIE) luminogen is obtained by dimerizing acridin-9(10H)-one (Ac), an aggregation-caused quenching (ACQ) effect monomer via an N─N bond and forming 9H,9'H-[10,10'-biacridine]-9,9'-dione (DiAc) with D symmetry. The quenching of DiAc in solution is ascribed to the enhanced basicity promoting hydrogen bonding and then a hydrogen abstraction (HA) reaction and/or an unallowed transition in frontier orbitals with the same symmetry facilitating intersystem crossing. It is found that emissive Ac is one product of the non-emissive DiAc solution in the HA reaction activated by UV irradiation.
View Article and Find Full Text PDFACS Appl Polym Mater
December 2024
IMEM-BRT Group, Departament d'Enginyeria Química, EEBE, Universitat Politécnica de Catalunya, C/Eduard Maristany, 10-14, 08019 Barcelona, Spain.
The transition from insulator to electro-responsive has been successfully achieved by earlier studies for some inorganic materials by applying external stimuli that modify their 3D and/or electronic structures. In the case of insulating polymers, this transition is frequently accomplished by mixing them with other electroactive materials, even though a few physical treatments that induce suitable chemical modifications have also been reported. In this work, a smart approach based on the application of an electro-thermal reorientation process followed by a charged gas activation treatment has been developed for transforming insulating 3D printed polymers into electro-responsive materials.
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