Synthesis of Ca(PF), formed via nitrosonium oxidation of calcium.

Chem Commun (Camb)

Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK.

Published: April 2017

The development of rechargeable Ca-ion batteries as an alternative to Li systems has been limited by the availability of suitable electrolyte salts. We present the synthesis of complexes of Ca(PF) (a key potential Ca battery electrolyte salt) via the treatment of Ca metal with NOPF, and explore their conversion to species containing POF under the reaction conditions.

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Source
http://dx.doi.org/10.1039/c7cc01938fDOI Listing

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